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RESEARCH PRODUCT

Pressure induced changes in the Raman spectra of liquidn-alkanes and perfluoro-n-alkanes

Gert StroblR. EckelH. Schwickert

subject

N alkanessymbols.namesakeColloid and Surface ChemistryPolymers and PlasticsChemistryMaterials ChemistryAnalytical chemistrysymbolsPhysical and Theoretical ChemistryRaman spectroscopyConformational isomerismLine (formation)

description

The main effect of pressures up to 6 kbar on the Raman spectra of liquidn-alkanes and perfluoro-n-alkanes is a reduction of line widths indicative for a slowing-down of rotational motions about the long axes. There is no evidence for a change in the conformer populations.

https://doi.org/10.1007/bf01422590