6533b827fe1ef96bd1286495
RESEARCH PRODUCT
High-resolution spectrum of the ν+ν(E),ν+ν(E),ν+ν(A), and ν3+ν4(A2) bands of the PH3 molecule: assignments and preliminary analysis
V.a. KozinskaiaL. PluchartShui-ming HuQingshi ZhuClaude LeroySheng-gui HeElena Sergeevna BekhterevaJing-jing ZhengO.n. Ulenikovsubject
PhysicsRadiation010304 chemical physicsAbsorption spectroscopyInfraredInfrared spectroscopy010402 general chemistry01 natural sciencesAtomic and Molecular Physics and OpticsSpectral line0104 chemical sciencessymbols.namesakeNuclear magnetic resonanceFourier transformExcited state0103 physical sciencessymbolsMoleculeAtomic physicsSpectroscopySpectroscopydescription
Abstract The high-resolution (0.005 cm −1 ) Fourier transform infrared spectrum of PH3 is recorded in the region between 3280 and 3580 cm −1 where the following bands are located: ν 1 +ν 4 (E), ν 3 +ν 4 (E), ν 3 +ν 4 (A 1 ) , forbidden on symmetry band ν3+ν4(A2), and very weak bands ν 1 +ν 2 (A 1 ), ν 2 +ν 3 (E) . Transitions are assigned to the first four ones. Vibrational analysis of known experimental data is made.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-02-01 | Journal of Quantitative Spectroscopy and Radiative Transfer |