6533b827fe1ef96bd12866a1
RESEARCH PRODUCT
Bis(3,5-dimethyl-1H-pyrazolyl)selenide--a new bidentate bent connector for preparation of 1D and 2D co-ordination polymers.
Matti HaukkaVadim A. PavlenkoIgor O. FritskyHenryk KozłowskiPhilipp GütlichRoland KrämerMaksym SeredukMaksym Seredyuksubject
chemistry.chemical_classificationDenticityBent molecular geometryInorganic chemistryPolymerMagnetic susceptibilityIonInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryTransition metalSelenideMössbauer spectroscopydescription
The synthesis and description of eight polymeric complexes formed by transition metals with the bifurcated ligand bis(3,5-dimethyl-1H-pyrazolyl)selenide are discussed together with X-ray crystal analysis as well as variable temperature magnetic susceptibility and characterization by Mossbauer spectroscopy. Preferable types of binding patterns of the ligand were determined, which include a variation of the bridging modes (cis- and trans-) and of the separation length, where the latter parameter together with bending of the ligand molecule were found to be dependent on the type of co-ordination geometry of the central atom and the nature of the anion. A strategy for increasing the structure dimensionality was explored using bridging properties of anions yielding 2D hybrid organic-inorganic polymers.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-07-20 | Dalton transactions (Cambridge, England : 2003) |