Selective recognition of aromatic hydrocarbons by endo-functionalized molecular tubes via C/N-H⋅⋅⋅π interactions

6533b827fe1ef96bd12868ce

RESEARCH PRODUCT

Selective recognition of aromatic hydrocarbons by endo-functionalized molecular tubes via C/N-H⋅⋅⋅π interactions

Guo-bao Huang Wei-er Liu Arto Valkonen Huan Yao Kari Rissanen Wei Jiang

subject

hydrogen bond macrocycles vety host-guest chemistry aromatic hydrocarbon molekyylidynamiikka molecular recognition hiilivedyt

description

Molecular recognition of aromatic hydrocarbons by four endo-functionalized molecular tubes has been studied by 1H NMR spectroscopy, computational methods, and single crystal X-ray crystallography. The binding selectivity is rationalized by invoking shape complementarity and dipole alignment. The non-covalent interactions are proved to predominantly be C/N-H⋅⋅⋅π interactions. peerReviewed

year	journal	country	edition	language
2018-01-01

http://urn.fi/URN:NBN:fi:jyu-201801151206

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