Evaluation of the interelemental effect in X-ray fluorescence analysis by the total addition method

6533b827fe1ef96bd1286e24

RESEARCH PRODUCT

Evaluation of the interelemental effect in X-ray fluorescence analysis by the total addition method

V. Peris Martinez F. Bosch Mossi F. Bosch Reig J. V. Gimeno Adelantado

subject

Fluorescence intensity Analyte chemistry Calibration curve Attenuation coefficient Standard addition Analytical chemistry chemistry.chemical_element X-ray fluorescence Tin Biochemistry Fluorescence Analytical Chemistry

description

An algorithm for quantifying interelemental effects in X-ray fluorescence techniques is developed. By applying an addition process, the ratio between the mass absorption coefficients of the analyte and the unknown sample (μi*/μs*) is calculated to correct the fluorescence intensity of the element to be determined and linearize the I-c calibration plot. This coefficient can be calculated graphically and numerically. The method is applied to the determination of tin in lead alloys with good results over wide concentration ranges.

year	journal	country	edition	language
1992-01-01	Fresenius' Journal of Analytical Chemistry

https://doi.org/10.1007/bf00322173

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