6533b827fe1ef96bd1286f5d

RESEARCH PRODUCT

Hackmanite—The Natural Glow-in-the-Dark Material

Eero LaakkonenCecilia AgamahTimo SaarinenPhilippe SmetJoachim LindblomIsabella NorrboAxel EmmermannSami VuoriLudo Van GoethemPauline ColinetJohan LindénMika LastusaariDavid Van Der HeggenLiana Key Okada NakamuraTangui Le BahersHenk VrielinckJari KonuTero LaihinenJosé Miranda De Carvalho

subject

Materials scienceGeneral Chemical Engineeringchemistry.chemical_element02 engineering and technologyNatural mineral010402 general chemistry01 natural sciencesNatural (archaeology)Synthetic materialsSODALITEchemistry.chemical_compoundPersistent luminescenceMaterials ChemistryTUGTUPITESPECTRACOLORluminesenssiIRONStrontium aluminate[CHIM.MATE]Chemical Sciences/Material chemistryOPTICAL-PROPERTIESGeneral ChemistryRESONANCE021001 nanoscience & nanotechnology0104 chemical sciencesAfterglow[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryCENTERSPhysics and AstronomychemistryChemical physicsLUMINESCENCE0210 nano-technologyEuropiumLuminescence

description

“Glow-in-the-dark” materials are known to practically everyone who has ever traveled by airplane or cruise ship, since they are commonly used for self-lit emergency exit signs. The green afterglow, persistent luminescence (PeL), is obtained from divalent europium doped to a synthetic strontium aluminate, but there are also some natural minerals capable of afterglow. One such mineral is hackmanite, the afterglow of which has never been thoroughly investigated, even if its synthetic versions can compete with some of the best commercially available synthetic PeL materials. Here we combine experimental and computational data to show that the white PeL of natural hackmanite is generated and controlled by a very delicate interplay between the natural impurities present. The results obtained shed light on the PeL phenomenon itself thus giving insight into improving the performance of synthetic materials. peerReviewed

https://doi.org/10.1021/acs.chemmater.0c02554