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RESEARCH PRODUCT
Solid-State Aggregation of Metallacyclophane-Based MnIICuII One-Dimensional Ladders
Miguel JulveCatalina Ruiz‐pérezEmilio PardoFrancesc LloretThais GranchaYves JournauxJoan CanoJesús Ferrando-soriaLaura Cañadillas-delgadoJorge Pasánsubject
Models Molecularchemistry.chemical_classificationManganeseMolecular StructureTemperatureSolid-statePolymerCrystallography X-RayInorganic ChemistryCrystallographychemistryOrganometallic CompoundsAntiferromagnetismPhysical and Theoretical ChemistryLayer (electronics)Copperdescription
Two distinct one-dimensional (1) and two-dimensional (2) mixed-metal-organic polymers have been synthesized by using the "complex-as-ligand" strategy. The structure of 1 consists of isolated ladderlike Mn(II)(2)Cu(II)(2) chains separated from each other by neutral Mn(II)(2) dimers, whereas 2 possesses an overall corrugated layer structure built from additional coordinative interactions between adjacent Mn(II)(2)Cu(II)(2) ladders. Interestingly, 1 and 2 show overall ferri- and antiferromagnetic behavior, respectively, as a result of their distinct crystalline aggregation in the solid state.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-06-20 | Inorganic Chemistry |