6533b828fe1ef96bd12882b5

RESEARCH PRODUCT

Sequential Nucleophilic−Electrophilic Reactions Selectively Produce Isomerically Pure Nona‐ B ‐Substituted o ‐Carborane Derivatives

Clara ViñasFrancesc TeixidorReijo SillanpääGemma BarberàRaikko Kivekäs

subject

010405 organic chemistryChemistrychemistry.chemical_element010402 general chemistryIodine01 natural sciences0104 chemical sciences3. Good healthInorganic ChemistryReaction sequenceNucleophileElectrophileCarboraneOrganic chemistryBoron

description

Nine equal substituents on the intensively studied o-carborane have been obtained for the first time by a combined nucleophilic-electrophilic reaction sequence. Iodine and methyl groups have been introduced to prove the generality of the method. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

https://doi.org/10.1002/ejic.200390195