6533b828fe1ef96bd128843a

RESEARCH PRODUCT

Excitation processes of the blue luminescence in crystalline SiO 2 probed by synchrotron radiation measurements

Franco Mario GelardiAnatoly N. TrukhinRoberto BoscainoMarco CannasSimonpietro Agnello

subject

Range (particle radiation)ChemistryExcited stateExcitonSynchrotron radiationSpontaneous emissionAtomic physicsCondensed Matter PhysicsLuminescenceSpectroscopyExcitation

description

Luminescence properties of crystalline α-quartz were investigated by time-resolved spectroscopy under pulsed synchrotron radiation excitation in the vacuum ultraviolet range. Our results evidence that two emission bands overlap at 2.7 eV, both being observed only at low temperature. The first contribution is excited by band-to-band transition and is related to the radiative recombination of a self trapped exciton occurring in a time scale of a few ms, the second is associated with defects induced in quartz by γ- and β-radiation, is excited at 7.6 eV and its lifetime is 3.6 ns at T = 10 K. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)

https://doi.org/10.1002/pssc.200673793