6533b828fe1ef96bd1288cb9
RESEARCH PRODUCT
Diastereoselective synthesis of enantiomeric tertiary alcohols via nucleophilic additions to protected D- and L-erythrulose derivatives
J. Alberto MarcoMiguel CardaFlorenci V. GonzálezSantiago Rodríguezsubject
StereochemistryOrganic ChemistryDiastereomerErythruloseL-ERYTHRULOSECatalysisInorganic ChemistrySolventchemistry.chemical_compoundchemistryNucleophileReagentPhysical and Theoretical ChemistryEnantiomerTertiary alcoholsdescription
Abstract The diastereoselectivity of the addition of several organometallic reagents to the carbonyl group of protected D - and L -erythrulose derivatives has been investigated. Tertiary alcohols are stereoselectively formed, the diastereomeric ratio being markedly dependent on the reagent type, solvent and temperature.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1992-12-01 | Tetrahedron: Asymmetry |