6533b828fe1ef96bd1289097
RESEARCH PRODUCT
Reverse electrodialysis with NH4HCO3-water systems for heat-to-power conversion
Alessandro TamburiniMichael PapapetrouM. BevacquaGdm MicaleAndrea CipollinaAntonio Piacentinosubject
Settore ING-IND/26 - Teoria Dello Sviluppo Dei Processi ChimiciStripping (chemistry)Salinity gradient power (SGP)020209 energyAnalytical chemistry02 engineering and technology7. Clean energyThermolytic saltIndustrial and Manufacturing EngineeringWaste heat recovery unitReversed electrodialysisThermal0202 electrical engineering electronic engineering information engineeringElectrical and Electronic EngineeringClosed-loop reverse electrodialysiWaste heat recoveryAmmonium hydrogen carbonateCivil and Structural EngineeringPower densityHeat engineWaste managementChemistryMechanical EngineeringAmmonium hydrogen carbonate; Closed-loop reverse electrodialysis; Reverse ElectroDialysis Heat Engine (REDHE); Salinity gradient power (SGP); Thermolytic salts; Waste heat recovery; Civil and Structural Engineering; Building and Construction; Pollution; Energy (all); Mechanical Engineering; Industrial and Manufacturing Engineering; Electrical and Electronic EngineeringBuilding and ConstructionElectrodialysis021001 nanoscience & nanotechnologyPollution6. Clean waterEnergy (all)General EnergyReverse ElectroDialysis Heat Engine (REDHE)Electric power0210 nano-technologydescription
Abstract A Reverse ElectroDialysis Heat Engine (REDHE) system operating with “thermolytic” ammonium hydrogen-carbonate (NH4HCO3) aqueous solutions as working fluids is studied. The engine is constituted by (i) a RED unit to produce electric power by mixing the solutions at different salinity and (ii) a thermally-driven regeneration unit including a stripping and an absorption column to restore the initial salinity gradient thus closing the cycle. In the present work only the RED unit and the stripping column are taken into account. In particular, a simplified integrated process model for the whole cycle was developed: it consists of (i) a lumped parameter model for the RED unit validated with experimental data and (ii) a model developed via a process simulator to assess the thermal duty of the stripping column. The effect of operating conditions as solution concentrations and velocities was investigated by a sensitivity analysis. Under the best conditions (among those investigated), a power density of about 9 W/m2 of cell pair was predicted for the RED unit, and a maximum exergetic efficiency of about 22% was found for the whole cycle. A preliminary economic analysis of the process is also provided.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-10-01 |