6533b829fe1ef96bd1289a32
RESEARCH PRODUCT
Efficient growth of sub-micrometric MOF crystals inside the channels of AAO membranes
Mahmoud MaksoudMahmoud MaksoudStéphane BrandèsLaurent AruraultNans RoquesNans RoquesJean-pascal SutterJean-pascal Suttersubject
Whole membraneMaterials scienceCoordination polymerMatériauxInorganic chemistry[ SPI.MAT ] Engineering Sciences [physics]/Materialschemistry.chemical_elementCrystal growth02 engineering and technology010402 general chemistry01 natural sciencesCrystals[SPI.MAT]Engineering Sciences [physics]/Materialschemistry.chemical_compoundGeneral Materials Sciencechemistry.chemical_classificationRenewable Energy Sustainability and the EnvironmentSorptionAAO membranesGeneral ChemistryTricarboxylic acid[CHIM.MATE]Chemical Sciences/Material chemistry021001 nanoscience & nanotechnologyCopperSub-micrometric MOF0104 chemical sciencesMembranechemistry[ CHIM.MATE ] Chemical Sciences/Material chemistryAluminium oxide0210 nano-technologydescription
International audience; A dynamic step-by-step methodology has been implemented to grow the HKUST-1 porous coordination polymer inside commercial anodic aluminium oxide membranes. Efficient crystal growth is achieved from the membrane inner walls and over the whole membrane thickness when copper acetate colloidal suspensions and benzene tricarboxylic acid solutions are forced to flow through the membrane. Sorption properties of the HKUST-1 embedded in membranes show selectivity for CO2 over CO, CH4, O2 and N2 similar to the bulk material.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-03-21 |