6533b829fe1ef96bd128ab97
RESEARCH PRODUCT
Infrared and Mössbauer studies on adducts R3SnOH · R3MX (M = Sn, Pb; X = Pseudohalide)
F. Di BiancaNuccio BertazziG. C. StoccoGiuseppe Alonzosubject
Inorganic ChemistryCrystallographyHydrogen bondInfraredChemistryMössbauer spectroscopyInorganic chemistryMaterials Chemistrychemistry.chemical_elementPhysical and Theoretical ChemistryTinAdductdescription
Abstract The synthesis of the solid adducts Me3SnOH · Me3 SnNCO, Me3SnOH · Me3SnNCS, Me3SnOH · Me3PbN3, Ph3SnOH · Ph3SnN3 is reported. The compounds have been investigated by infrared and Mossbauer spectroscopy. Their structure probably consists of polymeric OH-R3Sn-X-R3Sn(Pb) chains in which hydroxyl and pseudohalide (X) groups are bridging pentacoordinate tin atoms. In contrast to the triphenyl compound, the trimethyl derivatives show evidence of hydrogen bonding between adjacent chains.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1975-01-01 | Inorganica Chimica Acta |