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RESEARCH PRODUCT
Zinc(II) complexes of amide- and urea-substituted 8-hydroxyquinolines
Patrick WeisMarkus AlbrechtKaren WittRoland FröhlichElina Wegeliussubject
Coordination polymerStereochemistrySolid-statechemistry.chemical_element8-HydroxyquinolineZincFluorescenceInorganic Chemistrychemistry.chemical_compoundchemistryAmidePolymer chemistryMaterials ChemistryUreaHydroxyquinolinesPhysical and Theoretical Chemistrydescription
Abstract A series of amide- and urea-substituted 8-hydroxyquinoline ligands 1–6-H are used for the formation of zinc(II) complexes. Hereby in general 2:1 complexes are obtained and the X-ray structure of [(3)2Zn] reveals the presence of a coordination polymer in the solid state. Only the derivatives of 7-amino-8-hydroxyquinoline 4-H and 5-H form trinuclear hexa-helical 6:3 complexes which exhibit interesting structural and NMR and fluorescence spectroscopic properties.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-12-01 | Inorganica Chimica Acta |