Search results for "8-Hydroxyquinoline"

showing 8 items of 8 documents

Gelation behavior of 5-chloro-8-hydroxyquinoline, an antituberculosis agent, in aqueous alcohol solutions

2012

It was shown that 5-chloro-8-hydroxyquinoline, an antituberculosis agent, gels aqueous alcohol solutions efficiently. Thermal stability and gel-to-sol transition temperature of 1% gel in CD3OD/D2O (2:1) was studied by 1H-NMR. Fibrous structures of four xerogels have been characterized by scanning electron microscope. peerReviewed

Microbiology (medical)gelScanning electron microscope5-kloori-8-hydroksikinoliinigel; 5-chloro-8-hydroxyquinoline; <em>Mycobacterium </em><em>tuberculosis</em>gelationBiochemistryMicrobiologyArticle5-chloro-8-hydroxyquinolinechemistry.chemical_compoundOrganic chemistryPharmacology (medical)Thermal stabilityGeneral Pharmacology Toxicology and Pharmaceuticsta116Aqueous alcoholgeelin muodostusTransition temperature5-chloro-8-hydoxyquinolinelcsh:RM1-950Antituberculosis agent8-HydroxyquinolineMycobacterium tuberculosisInfectious Diseaseslcsh:Therapeutics. PharmacologychemistryNuclear chemistryAntibiotics
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Solid State Structures of Amide-Substituted 8-Hydroxyquinoline Derivatives

2000

Abstract The amide substituted 8-hydroxyquinoline derivatives 3 and 4 form, in the solid state, hydrogen bonded polymers. Polymeric 3 adopts a helical conformation while 4 forms a double-stranded ladder-type structure.

chemistry.chemical_classificationHydrogenHydrogen bondOrganic ChemistryLow-barrier hydrogen bondSolid-statechemistry.chemical_element8-HydroxyquinolinePolymerBiochemistrySolid state structurechemistry.chemical_compoundchemistryAmideDrug DiscoveryPolymer chemistryOrganic chemistryTetrahedron
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Zinc(II) complexes of amide- and urea-substituted 8-hydroxyquinolines

2002

Abstract A series of amide- and urea-substituted 8-hydroxyquinoline ligands 1–6-H are used for the formation of zinc(II) complexes. Hereby in general 2:1 complexes are obtained and the X-ray structure of [(3)2Zn] reveals the presence of a coordination polymer in the solid state. Only the derivatives of 7-amino-8-hydroxyquinoline 4-H and 5-H form trinuclear hexa-helical 6:3 complexes which exhibit interesting structural and NMR and fluorescence spectroscopic properties.

Coordination polymerStereochemistrySolid-statechemistry.chemical_element8-HydroxyquinolineZincFluorescenceInorganic Chemistrychemistry.chemical_compoundchemistryAmidePolymer chemistryMaterials ChemistryUreaHydroxyquinolinesPhysical and Theoretical ChemistryInorganica Chimica Acta
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Mono-aryltin(IV) and mono-benzyltin(IV) complexes with pyridine-2-carboxylic acid and 8-hydroxyquinoline. X-ray structure of p-chloro-phenyl-tris(8-q…

1999

Abstract Complexes RSn(O2CPy)3·2H2O and RSn(Ox)3, (PyCOOH=pyridine-2-carboxylic acid, HOx=8-hydroxyquinoline, R=o- and p-Tolyl, o- and p-ClC6H4=o- and p-ClPh, o-ClC6H4CH2=o-ClBenzyl; besides, R=Ph in RSn(Ox)3) have been synthesized and characterized by elemental analysis and determination of molecular weights in CHCl3 solutions. The structure of p-ClPhSn(Ox)3·2CHCl3 has been determined by X-ray diffractometry. The 7-coordinated tin atom of the monomeric compound is in the center of a pentagonal bipyramid formed by (p-ClPh)C and O and N atoms of the chelating Ox− ligands. The latter type of structure would hold for all complexes according to 119Sn Mossbauer (including the determination of th…

chemistry.chemical_classificationDenticityChemistryStereochemistryLigandCarboxylic acidOrganic ChemistryInfrared spectroscopy8-HydroxyquinolineBiochemistryInorganic ChemistryCrystallographychemistry.chemical_compoundPentagonal bipyramidal molecular geometryPyridineMaterials ChemistryChelationPhysical and Theoretical ChemistryJournal of Organometallic Chemistry
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Effective Removal and Mineralization of 8-Hydroxyquinoline-5-sulfonic Acid through a Pressurized Electro-Fenton-like Process with Ni−Cu−Al Layered Do…

2020

Ni−Cu−Al layered double hydroxide (Ni−Cu−Al LDH) was proposed as an electro‐Fenton‐like catalyst for 8‐hydroxyquinoline‐5‐sulfonic acid (8‐HQS) removal in water. The properties of the prepared catalysts were characterized by using X‐ray, SEM and EDAX analyses. The effect of numerous operative parameters on the removal of 8‐HQS and total organic carbon (TOC) was studied. Very high level removal of both 8‐HQS and TOC (87 and 79 %, respectively) were obtained by using a pressurized electro‐Fenton‐like process (PrEFL‐LDH) at P=10 bars, using a Ti/IrO2‐Ta2O5 anode for 6 h. The process presented good performances in a large range of pH (3–10) and gave better removals of 8‐HQS and TOC with respect…

chemistry.chemical_classificationchemistry.chemical_compoundChemistry8-hydroxyquinoline-5-sulfonic acid heterogeneous catalysis Ni−Cu−Al layered double hydroxide nitrogen heterocycles pressurized-electro-FentonElectrochemistryHydroxide8-HydroxyquinolineMineralization (soil science)Sulfonic acidSettore ING-IND/27 - Chimica Industriale E TecnologicaHeterogeneous catalysisCatalysisNuclear chemistry
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CCDC 133180: Experimental Crystal Structure Determination

2003

Related Article: M.Albrecht, K.Witt, E.Wegelius, K.Rissanen|2000|Tetrahedron|56|591|doi:10.1016/S0040-4020(99)01057-1

Space GroupCrystallographyCrystal SystemCrystal Structure7-Acetamido-8-hydroxyquinolineCell ParametersExperimental 3D Coordinates
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CCDC 133179: Experimental Crystal Structure Determination

2003

Related Article: M.Albrecht, K.Witt, E.Wegelius, K.Rissanen|2000|Tetrahedron|56|591|doi:10.1016/S0040-4020(99)01057-1

Space GroupCrystallography2-(N-n-Hexylcarboxamide)-8-hydroxyquinolineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 633849: Experimental Crystal Structure Determination

2007

Related Article: M.Albrecht, Triyanti, S.Schiffers, O.Osetska, G.Raabe, T.Wieland, L.Russo, K.Rissanen|2007|Eur.J.Org.Chem.|2007|2850|doi:10.1002/ejoc.200700130

Space GroupCrystallographyCrystal SystemCrystal Structure57-Dibromo-8-hydroxyquinoline-2-carboxylic acid dimethylsulfoxide solvateCell ParametersExperimental 3D Coordinates
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