Nucleophilic Additions of the Cyanide Anion to 4,4-Dichloro-1,1-Diphenyl-2-Azabuta-1,3-Diene

6533b829fe1ef96bd128aeab

RESEARCH PRODUCT

Nucleophilic Additions of the Cyanide Anion to 4,4-Dichloro-1,1-Diphenyl-2-Azabuta-1,3-Diene

Gérard Schmitt Olivier Blacque Sandrine Jacquot-rousseau Marek M. Kubicki Bernard Laude

subject

chemistry.chemical_compound chemistry Nucleophile Diene Potassium cyanide General Chemistry Medicinal chemistry Cyanide anion

description

The unexpected formation of a 2H-pyrrole by reaction of potassium cyanide with 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene and the mechanism of this reaction are described and the structures of the product and a trapped intermediate confirmed by X-ray crystallographic studies.

year	journal	country	edition	language
2002-04-01	Journal of Chemical Research

https://doi.org/10.3184/030823402103171681

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