6533b82afe1ef96bd128b607

RESEARCH PRODUCT

Activité catalytique de dérivés du ruthénium(II) contenant le ligand triméthylyphosphine

E. HademerPierre H. DixneufHellmut SingerU. Oehmichen

subject

StereochemistryLigandOrganic Chemistrychemistry.chemical_elementAlcoholBiochemistryMedicinal chemistryCatalysisRutheniumInorganic Chemistrychemistry.chemical_compoundchemistryMaterials ChemistryPhysical and Theoretical Chemistry

description

Abstract Three ruthenium(II) complexes containing the ligand PMe3,:RuCl2(PMe3)(C6H6) (I), RuCl2(PMe3)4 (II) and RuCl2(CO)2(PMe3)2 (III) were prepared and their catalytic properties investigated. They showed activity as hydrogenation catalysts in the presence of Me2NH · BH3 and alcohol and the activity increased significantly in the order I

yearjournalcountryeditionlanguage
1979-10-01Journal of Organometallic Chemistry
https://doi.org/10.1016/s0022-328x(00)94235-9