0000000000659004

AUTHOR

U. Oehmichen

showing 2 related works from this author

Activité catalytique de dérivés du ruthénium(II) contenant le ligand triméthylyphosphine

1979

Abstract Three ruthenium(II) complexes containing the ligand PMe3,:RuCl2(PMe3)(C6H6) (I), RuCl2(PMe3)4 (II) and RuCl2(CO)2(PMe3)2 (III) were prepared and their catalytic properties investigated. They showed activity as hydrogenation catalysts in the presence of Me2NH · BH3 and alcohol and the activity increased significantly in the order I

StereochemistryLigandOrganic Chemistrychemistry.chemical_elementAlcoholBiochemistryMedicinal chemistryCatalysisRutheniumInorganic Chemistrychemistry.chemical_compoundchemistryMaterials ChemistryPhysical and Theoretical ChemistryJournal of Organometallic Chemistry
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Die alkoholyse des triethylsilans katalysiert von [(CH3)3P]2Ru(CO)2Cl2

1983

Abstract [(CH 3 ) 3 Pl 2 Ru(CO) 2 Cl 2 is an effective catalyst for the reaction of alcohols with triethylsilane. The rate of this reaction varies with the substituents in the hydroxy compound; it is fastest for short primary alcohols. Even in the presence of groups which can be hydrosilated (CC triple or double bonds, as well as ketones), a hydroxy group reacts preferably and completely with the silane. Kinetic experiments have been performed with the system Et 3 SiH/CH 3 CH(OH)COOEt/Ru complex.

chemistry.chemical_classificationPrimary (chemistry)Double bondChemistryOrganic ChemistryHydroxy groupBiochemistryMedicinal chemistrySilaneHydroxy compoundCatalysisInorganic Chemistrychemistry.chemical_compoundMaterials ChemistryOrganic chemistryPhysical and Theoretical ChemistryTriethylsilaneJournal of Organometallic Chemistry
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