6533b873fe1ef96bd12d4ae7

RESEARCH PRODUCT

Die alkoholyse des triethylsilans katalysiert von [(CH3)3P]2Ru(CO)2Cl2

U. OehmichenHellmut Singer

subject

chemistry.chemical_classificationPrimary (chemistry)Double bondChemistryOrganic ChemistryHydroxy groupBiochemistryMedicinal chemistrySilaneHydroxy compoundCatalysisInorganic Chemistrychemistry.chemical_compoundMaterials ChemistryOrganic chemistryPhysical and Theoretical ChemistryTriethylsilane

description

Abstract [(CH 3 ) 3 Pl 2 Ru(CO) 2 Cl 2 is an effective catalyst for the reaction of alcohols with triethylsilane. The rate of this reaction varies with the substituents in the hydroxy compound; it is fastest for short primary alcohols. Even in the presence of groups which can be hydrosilated (CC triple or double bonds, as well as ketones), a hydroxy group reacts preferably and completely with the silane. Kinetic experiments have been performed with the system Et 3 SiH/CH 3 CH(OH)COOEt/Ru complex.

yearjournalcountryeditionlanguage
1983-02-01Journal of Organometallic Chemistry
https://doi.org/10.1016/0022-328x(83)89532-1