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RESEARCH PRODUCT
Molecular Motion, Defect Structures and Phase Transitions in Oligomer Crystals
H. SchwickertT. TrzebiatowskiGert Stroblsubject
Phase transitionSuperposition principleCrystallographychemistry.chemical_compoundChain (algebraic topology)ChemistryGeneral Chemical EngineeringMolecular motionMoleculeOligomerdescription
Defect structures in the high temperature modifications of oligomer crystals can generally be discribed as a superposition of chain rotations, longitudinal shifts of the molecules and the occurrence of conformational defects. Applying a suitable combination of experimental techniques it is possible to discriminate between the different components of disorder. This is demonstrated in a discussion of results obtained on n-alkanes, cycloalkanes and perfluoro-n-alkanes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1983-03-01 | Berichte der Bunsengesellschaft für physikalische Chemie |