6533b82afe1ef96bd128ca47

RESEARCH PRODUCT

Solution-processable green phosphorescent iridium(III) complexes bearing 3,3,3-triphenylpropionic acid fragment for use in OLEDs

Kaspars TraskovskisAivars VembrisValdis Kokars

subject

Materials sciencePhotoluminescencechemistryFragment (computer graphics)LigandOLEDChemical modificationchemistry.chemical_elementIridiumGreen-lightPhosphorescencePhotochemistry

description

New solution-processable materials based on well-known green iridium(III) heteroleptic complexes (ppy) 2 Ir(acac) and (ppy) 2 Ir(pic) were acquired by chemical modification of ppy ligand with functionable hydroxyl groups and subsequent esterification with 3,3,3-triphenylpropionic acid fragment. Photoluminescence quantum efficiencies up to 0.90 were measured for the compounds in solution. Emission characteristics in pure solid films and different guest-host systems with hole transporting materials were investigated. Green light emitting OLEDs (organic light emitting devices) was prepared and characterized.

https://doi.org/10.1117/12.2306806