6533b82bfe1ef96bd128ce0f
RESEARCH PRODUCT
Solid‐state NMR Spectroscopy of Iodine(I) Complexes
Jas S. WardElina I. SievänenKari Rissanensubject
jodihalogenbondBarluengareagentOrganic Chemistrykiinteän olomuodon kemiaGeneral Chemistrycationexchangeiodine(I)Biochemistrysolid-statedescription
Solid-state NMR has been applied to a series of Barluenga-type iodine(I) [L-I-L]PF6 (L=pyridine, 4-ethylpyridine, 4-dimethylaminopyridine, isoquinoline) complexes as their hexafluorophosphate salts, as well as their respective non-liquid ligands (L), their precursor silver(I) complexes, and the respective N-methylated pyridinium and quinolinium hexafluorophoshate salts. These results are compared and contrasted to the corresponding solution studies and single-crystal X-ray structures. As the first study of its kind on the solid-state NMR behavior of halogen(I) complexes, practical considerations are also discussed to encourage wider utilization of this technique in the future. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2023-02-06 | Chemistry – An Asian Journal |