Adsorption equilibria of water vapor on cork.

6533b82bfe1ef96bd128ce80

RESEARCH PRODUCT

Adsorption equilibria of water vapor on cork.

David Chassagne Laurent Brachais Sonia Lequin Régis D. Gougeon Thomas Karbowiak Jean-pierre Bellat

subject

02 engineering and technology Calorimetry Cork engineering.material 010402 general chemistry 01 natural sciences Quercus Adsorption medicine ComputingMilieux_MISCELLANEOUS Chemistry Water General Chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences Thermogravimetry Hysteresis [ PHYS.PHYS.PHYS-CHEM-PH ] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Solid-state nuclear magnetic resonance Chemical engineering engineering Plant Bark Physical chemistry Thermodynamics [PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Adsorption Swelling medicine.symptom 0210 nano-technology General Agricultural and Biological Sciences Cork Water vapor

description

International audience; We report here for the first time a complete thermodynamic study of water vapor adsorption on crude cork powder and plate. Adsorption−desorption isotherms were accurately measured by thermogravimetry at 283, 298, and 313 K in a large range of relative pressure. Adsorption enthalpies were determined by calorimetry as a function of loading. Adsorption−desorption isotherms exhibit a hysteresis due to the swelling of the material. The influence of the presence of lenticels on the adsorption properties of cork is found to be negligible. A detailed analysis and interpretation of adsorption data allow proposal of an adsorption mechanism in two steps. (i) First, water adsorbs on hydrophilic sites constituted by hydroxyl and methoxyl groups. (ii) Then water adsorption continues by clusters formation around the hydrophilic sites.

year	journal	country	edition	language
2010-01-01	Journal of agricultural and food chemistry

10.1021/jf9039364 https://pubmed.ncbi.nlm.nih.gov/20192215

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