Heterogeneous Sonogashira Coupling over Nanostructured SiliaCat Pd(0)

6533b82bfe1ef96bd128cef0

RESEARCH PRODUCT

Heterogeneous Sonogashira Coupling over Nanostructured SiliaCat Pd(0)

Rosaria Ciriminna Genevieve Gingras Valerica Pandarus François Béland Piera Demma Carà Mario Pagliaro

subject

Renewable Energy Sustainability and the Environment Heterogeneou General Chemical Engineering Aryl Sonogashira coupling Halide Sonogashira coupling Pd catalysi General Chemistry Photochemistry Catalysis SiliaCat chemistry.chemical_compound Sol−gel chemistry Phenylacetylene Microwave irradiation Environmental Chemistry Leaching (metallurgy)Sol-gel

description

Sol–gel entrapped catalyst SiliaCat Pd(0) heterogeneously mediates the Sonogoashira coupling of different aryl halides and phenylacetylene either under thermal conditions or, much more efficiently, under microwave irradiation, affording good conversions of coupled products. Leaching of valued Pd is limited, and the catalyst can be reused.

year	journal	country	edition	language
2012-10-02	ACS Sustainable Chemistry & Engineering

https://doi.org/10.1021/sc300083v

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