6533b82cfe1ef96bd128eaff

RESEARCH PRODUCT

{Bis[2-(diisopropylphosphanyl)ethyl]amine}carbonyl(tetrahydroborato)cobalt(I)

Andrea CingolaniAnke SpannenbergMatthias BellerKathrin Junge

subject

crystal structureLigandchemistry.chemical_elementcolbalt pincer complesCrystal structure010402 general chemistry010403 inorganic & nuclear chemistryBorohydride01 natural sciencesMedicinal chemistry0104 chemical sciencesPincer movementchemistry.chemical_compoundchemistryborohydridelcsh:QD901-999Amine gas treatinglcsh:CrystallographyCobaltCarbon monoxideCoordination geometry

description

In the structure of title borohydride pincer complex, [Co(BH4)(C16H37NP2)(CO)], the cobalt(I) metal exhibits a distorted square-pyramidal coordination geometry with the basal positions occupied by the P and N atoms of the tridentate ligand and by the C atom of the carbon monoxide ligand. In the crystal, molecules interact only by van der Waals forces.

yearjournalcountryeditionlanguage
2018-03-28IUCrData
10.1107/s2414314618004716http://scripts.iucr.org/cgi-bin/paper?S2414314618004716