6533b82cfe1ef96bd128f666

RESEARCH PRODUCT

A missing member in the family of chalcogenophene-substituted 2,2′:6′,2″-terpyridine: 4′-(tellurophen-2-yl)-2,2′:6′,2″-terpyridine, its Ru(II) complex and its electropolymerization as a thin film

Et Taouil AbdeslamJérôme HussonLaurent Guyard

subject

chemistry.chemical_classificationChemistryGeneral Chemical Engineering02 engineering and technologyPolymer010402 general chemistry021001 nanoscience & nanotechnologyMass spectrometryElectrochemistry01 natural sciences0104 chemical sciencesAnalytical Chemistrychemistry.chemical_compoundElectrochromismPolymer chemistryElectrochemistry[CHIM]Chemical SciencesThin filmTerpyridineHomoleptic0210 nano-technologyDerivative (chemistry)ComputingMilieux_MISCELLANEOUS

description

Abstract The new terpyridine derivative 4’-(tellurophen-2-yl)-2,2′:6′,2″-terpyridine and its homoleptic Ru(II) complex have been prepared and characterized by different techniques (NMR, UV–Vis, mass spectrometry). Additionally, a thin polymer film was obtained through electrochemical oxidation and coupling of tellurophene moieties. The obtained organic coating showed very interesting electrochemical and electrochromic properties, thanks to its Ru(terpy)2 groups.

10.1016/j.jelechem.2019.113594https://hal.archives-ouvertes.fr/hal-02372710