0000000000356967

AUTHOR

Jérôme Husson

0000-0001-9053-9736

showing 2 related works from this author

Terpyridine-based metallopolymer thin films as active layer in ammonia sensor device

2016

International audience; A metal-containing polymer has been prepared by electropolymerization of an homoleptic Ru(II)-terpyridine complex bearing pyrrole heterocycles. The polymer is obtained as a thinfilm at the surface ofelectrodes, and has been characterized by electrochemical measurements, XPS and microscopy. It hasbeen shown that this polymer acts as an active gas sensitive layer since it enables the detection of anammonia gasflow through layer’s resistivity measurements.

[INFO.INFO-DS]Computer Science [cs]/Data Structures and Algorithms [cs.DS]Nanotechnology02 engineering and technology010402 general chemistry01 natural sciences[SPI.AUTO]Engineering Sciences [physics]/Automatic[SPI.MAT]Engineering Sciences [physics]/Materialschemistry.chemical_compoundX-ray photoelectron spectroscopyMaterials ChemistryThin filmHomoleptic[SPI.NANO]Engineering Sciences [physics]/Micro and nanotechnologies/Microelectronicschemistry.chemical_classification[SPI.ACOU]Engineering Sciences [physics]/Acoustics [physics.class-ph]ChemistryMechanical EngineeringMetals and AlloysPolymer021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesElectronic Optical and Magnetic MaterialsActive layerChemical engineeringMechanics of MaterialsElectrodeTerpyridine0210 nano-technology[PHYS.ASTR]Physics [physics]/Astrophysics [astro-ph]Layer (electronics)
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A missing member in the family of chalcogenophene-substituted 2,2′:6′,2″-terpyridine: 4′-(tellurophen-2-yl)-2,2′:6′,2″-terpyridine, its Ru(II) comple…

2019

Abstract The new terpyridine derivative 4’-(tellurophen-2-yl)-2,2′:6′,2″-terpyridine and its homoleptic Ru(II) complex have been prepared and characterized by different techniques (NMR, UV–Vis, mass spectrometry). Additionally, a thin polymer film was obtained through electrochemical oxidation and coupling of tellurophene moieties. The obtained organic coating showed very interesting electrochemical and electrochromic properties, thanks to its Ru(terpy)2 groups.

chemistry.chemical_classificationChemistryGeneral Chemical Engineering02 engineering and technologyPolymer010402 general chemistry021001 nanoscience & nanotechnologyMass spectrometryElectrochemistry01 natural sciences0104 chemical sciencesAnalytical Chemistrychemistry.chemical_compoundElectrochromismPolymer chemistryElectrochemistry[CHIM]Chemical SciencesThin filmTerpyridineHomoleptic0210 nano-technologyDerivative (chemistry)ComputingMilieux_MISCELLANEOUS
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