6533b7dafe1ef96bd126e3e5

RESEARCH PRODUCT

Terpyridine-based metallopolymer thin films as active layer in ammonia sensor device

Jean-yves RauchEmmanuelle BrunolAbdeslam Et TaouilJérôme HussonJean-baptiste SanchezBouzid NaidjiLaurent GuyardFranck Berger

subject

[INFO.INFO-DS]Computer Science [cs]/Data Structures and Algorithms [cs.DS]Nanotechnology02 engineering and technology010402 general chemistry01 natural sciences[SPI.AUTO]Engineering Sciences [physics]/Automatic[SPI.MAT]Engineering Sciences [physics]/Materialschemistry.chemical_compoundX-ray photoelectron spectroscopyMaterials ChemistryThin filmHomoleptic[SPI.NANO]Engineering Sciences [physics]/Micro and nanotechnologies/Microelectronicschemistry.chemical_classification[SPI.ACOU]Engineering Sciences [physics]/Acoustics [physics.class-ph]ChemistryMechanical EngineeringMetals and AlloysPolymer021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesElectronic Optical and Magnetic MaterialsActive layerChemical engineeringMechanics of MaterialsElectrodeTerpyridine0210 nano-technology[PHYS.ASTR]Physics [physics]/Astrophysics [astro-ph]Layer (electronics)

description

International audience; A metal-containing polymer has been prepared by electropolymerization of an homoleptic Ru(II)-terpyridine complex bearing pyrrole heterocycles. The polymer is obtained as a thinfilm at the surface ofelectrodes, and has been characterized by electrochemical measurements, XPS and microscopy. It hasbeen shown that this polymer acts as an active gas sensitive layer since it enables the detection of anammonia gasflow through layer’s resistivity measurements.

10.1016/j.synthmet.2016.09.006https://hal.archives-ouvertes.fr/hal-02131231