6533b82cfe1ef96bd128f683
RESEARCH PRODUCT
Hybrid Magnetic Multilayers by Intercalation of Cu(II) Phthalocyanine in LDH Hosts
Carlos Marti-gastaldoGonzalo AbellánEugenio CoronadoFilippo BusoloAntonio Riberasubject
NialMaterials scienceIntercalation (chemistry)Inorganic chemistrychemistry.chemical_element02 engineering and technologyengineering.material010402 general chemistry01 natural sciencesParamagnetismchemistry.chemical_compoundPhysical and Theoretical Chemistrycomputer.programming_languageLayered double hydroxides021001 nanoscience & nanotechnologyCopper0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyGeneral EnergychemistryFerromagnetismPhthalocyanineengineeringDiamagnetism0210 nano-technologycomputerdescription
The intrinsic flexibility of layered double hydroxides (LDHs) has been here exploited to design hybrid multilayered materials by intercalation of the copper phthalocyaninetetrasulfonate (CuPcTs) complex in the interlamellar space offered by these layered hosts through a simple anion-exchange procedure. Taking advantage of their chemical versatility, two different LDHs, the diamagnetic ZnAl and the ferromagnetic NiAl, have been synthesized and characterized to explore the differences in the magnetic properties of the hybrids introduced by the intercalation of the paramagnetic complex.
year | journal | country | edition | language |
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2012-07-17 | The Journal of Physical Chemistry C |