Innentitelbild: Bidirectional Chemo&hyphen;Switching of Spin State in a Microporous Framework &lpar;Angew. Chem. 26&sol;2009&rpar;

6533b82cfe1ef96bd128fdc5

RESEARCH PRODUCT

Innentitelbild: Bidirectional Chemo&hyphen;Switching of Spin State in a Microporous Framework &lpar;Angew. Chem. 26&sol;2009&rpar;

Shigeyoshi Sakaki Ana B. Gaspar M. Carmen Muñoz Mikio Yamasaki Susumu Kitagawa Hideo Ando Ko Yoneda José Antonio Real Masaaki Ohba Yoshihide Nakao Gloria Agustí

subject

Physics Crystallography Spin states General Medicine Microporous material

description

Das chemische Schalten des Magnetismus in zwei Richtungen wurde in einem mikroporosen Koordinationspolymer mit Spin-Crossover-Einheiten beobachtet. M. Ohba, J. A. Real, S. Kitagawa und Mitarbeiter stellten in ihrer Zuschrift auf S. 4861 ff. magnetische Messungen vor, die belegen, dass die meisten Gastmolekule einen Ubergang des Netzwerks vom diamagnetischen Low-Spin- (rot) in den paramagnetischen High-Spin-Zustand (gelb) bewirken. Allein CS2 stabilisiert den Low-Spin-Zustand. Die induzierten Spinzustande werden auch nach Freisetzung der Gastspezies beibehalten.

year	journal	country	edition	language
2009-06-15	Angewandte Chemie

https://doi.org/10.1002/ange.200990136

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
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6533b82cfe1ef96bd128fdc5

RESEARCH PRODUCT

Innentitelbild: Bidirectional Chemo&amp;hyphen;Switching of Spin State in a Microporous Framework &amp;lpar;Angew. Chem. 26&amp;sol;2009&amp;rpar;

subject

description

Innentitelbild: Bidirectional Chemo&hyphen;Switching of Spin State in a Microporous Framework (Angew. Chem. 26/2009)