Heterocyclic photorearrangements. Photoinduced rearrangement of 3-styryl-1,2,4-oxadiazoles

6533b82cfe1ef96bd128fe18

RESEARCH PRODUCT

Heterocyclic photorearrangements. Photoinduced rearrangement of 3-styryl-1,2,4-oxadiazoles

Michelangelo Gruttadauria Silvestre Buscemi Giuseppe Cusmano

subject

Intramolecular reaction Bicyclic molecule medicine.drug_class Organic Chemistry Quinoline Photodissociation Carboxamide Ring (chemistry)Photochemistry Cis trans isomerization chemistry.chemical_compound chemistry medicine Moiety

description

The photochemical behaviour of 3-styryl-5-phenyl-(5-methyl)-1,2,4-oxadiazoles in methanol at 254 nm has been investigated. A photoinduced rearrangement to the quinoline system has been pointed out and explained as proceeding through an initial photolysis of the ring ON bond, followed by a six membered ring closure reaction involving the styryl moiety.

year	journal	country	edition	language
1990-05-01	Journal of Heterocyclic Chemistry

https://doi.org/10.1002/jhet.5570270408

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