6533b82cfe1ef96bd128feb8

RESEARCH PRODUCT

Atomically Precise Alkynyl- and Halide-Protected AuAg Nanoclusters Au78Ag66(C≡CPh)48Cl8 and Au74Ag60(C≡CPh)40Br12: The Ligation Effects of Halides

Guocheng DengFengjiao ChenXiting YuanBoon K. TeoLan-sun ZhengSami MalolaNanfeng ZhengHannu Häkkinen

subject

Inorganic Chemistry010405 organic chemistryChemistryPolymer chemistryHalidePhysical and Theoretical Chemistry010402 general chemistry01 natural sciences0104 chemical sciencesNanoclusters

description

Reported herein are the synthesis and structures of two high-nuclearity AuAg nanoclusters, namely, [Au78Ag66(C≡CPh)48Cl8]q− and [Au74Ag60(C≡CPh)40Br12]2–. Both clusters possess a three-concentric-s...

https://doi.org/10.1021/acs.inorgchem.0c03462