0000000000211569
AUTHOR
Boon K. Teo
Bulky Surface Ligands Promote Surface Reactivities of [Ag141X12(S-Adm)40]3+ (X=Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles
Surface ligands play important roles in controlling the size and shape of metal nanoparticles and their surface properties. In this work, we demonstrate that the use of bulky thiolate ligands, along with halides, as the surface capping agent promotes the formation of plasmonic multiple-twinned Ag nanoparticles with high surface reactivities. The title nanocluster [Ag141X12(S-Adm)40]3+ (where X = Cl, Br, I; S-Adm = 1-adamantanethiolate) has a multiple-shell structure with an Ag71 core protected by a shell of Ag70X12(S-Adm)40. The Ag71 core can be considered as 20 frequency-two Ag10 tetrahedra fused together with a dislocation that resembles multiple-twinning in nanoparticles. The nanocluster…
Atomically Precise Alkynyl-Protected Metal Nanoclusters as a Model Catalyst: Observation of Promoting Effect of Surface Ligands on Catalysis by Metal Nanoparticles
Metal nanoclusters whose surface ligands are removable while keeping their metal framework structures intact are an ideal system for investigating the influence of surface ligands on catalysis of metal nanoparticles. We report in this work an intermetallic nanocluster containing 62 metal atoms, Au34Ag28(PhC≡C)34, and its use as a model catalyst to explore the importance of surface ligands in promoting catalysis. As revealed by single-crystal diffraction, the 62 metal atoms in the cluster are arranged as a four-concentric-shell Ag@Au17@Ag27@Au17 structure. All phenylalkynyl (PA) ligands are linearly coordinated to the surface Au atoms with staple "PhC≡C-Au-C≡CPh" motif. Compared with reporte…
Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes.
Demonstrated herein are the preparation and crystallographic characterization of the family of fcc silver nanoclusters from Nichol’s cube to Rubik’s cube and beyond via ligand-control (thiolates and phosphines in this case). The basic building block is our previously reported fcc cluster [Ag14(SPhF2)12(PPh3)8] (1). The metal frameworks of [Ag38(SPhF2)26(PR′3)8] (22) and [Ag63(SPhF2)36(PR′3)8]+ (23), where HSPhF2 = 3,4-difluorothiophenol and R′ = alkyl/aryl, are composed of 2 × 2 = 4 and 2 × 2 × 2 = 8 metal cubes of 1, respectively. All serial clusters share similar surface structural features. The thiolate ligands cap the six faces and the 12 edges of the cube (or half cube) while the phosp…
Highly Robust but Surface-Active : An N-Heterocyclic Carbene-Stabilized Au25 Nanocluster
Surface organic ligands play a critical role in stabilizing atomically precise metal nanoclusters in solutions. However, it is still challenging to prepare highly robust ligated metal nanoclusters that are surface-active for liquid-phase catalysis without any pre-treatment. Now, an N-heterocyclic carbene-stabilized Au25 nanocluster with high thermal and air stabilities is presented as a homogenous catalyst for cycloisomerization of alkynyl amines to indoles. The nanocluster, characterized as [Au25(iPr2-bimy)10Br7]2+ (iPr2-bimy=1,3-diisopropylbenzimidazolin-2-ylidene) (1), was synthesized by direct reduction of AuSMe2Cl and iPr2-bimyAuBr with NaBH4 in one pot. X-ray crystallization analysis …
Tertiary Chiral Nanostructures from C‐H∙∙∙F Directed Assembly of Chiroptical Superatoms
Chiral hierarchical structures are universal in nature, whereas quite challenging to mimic in man-made synthesis. We report herein the synthesis and structure of tertiary chiral nanostructures with 100% optical purity. A novel synthetic strategy, using chiral reducing agent, R and S -BINAPCuBH 4 (BINAP is 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl), is developed to access to atomically precise, intrinsically chiral [Au 7 Ag 6 Cu 2 ( R - or S -BINAP) 3 (SCH 2 Ph) 6 ]SbF 6 nanoclusters in one-pot synthesis. The clusters represent the first tri-metallic superatoms with inherent chirality and fair stability. Both metal distribution (primary) and ligand arrangement (secondary) of the enantiomer…
From Symmetry Breaking to Unraveling the Origin of the Chirality of Ligated Au13Cu2 Nanoclusters
A general method, using mixed ligands (here diphosphines and thiolates) is devised to turn an achiral metal cluster, Au13Cu2, into an enantiomeric pair by breaking (lowering) the overall molecular symmetry with the ligands. Using an achiral diphosphine, a racemic [Au13Cu2(DPPP)3(SPy)6]+ was prepared which crystallizes in centrosymmetric space groups. Using chiral diphosphines, enantioselective synthesis of an optically pure, enantiomeric pair of [Au13Cu2((2r,4r)/(2s,4s)‐BDPP)3(SPy)6]+ was achieved in one pot. Their circular dichroism (CD) spectra give perfect mirror images in the range of 250–500 nm with maximum anisotropy factors of 1.2×10−3. DFT calculations provided good correlations wit…
Surface Coordination of Multiple Ligands Endows N‐Heterocyclic Carbene‐Stabilized Gold Nanoclusters with High Robustness and Surface Reactivity
Deciphering the molecular pictures of the multi-component and non-periodic organic-inorganic interlayer is a grand technical challenge. Here we show that the atomic arrangement of hybrid surface ligands on metal nanoparticles can be precisely quantified through comprehensive characterization of a novel gold cluster, Au 44 ( i Pr 2 -bimy) 9 (PA) 6 Br 8 , which features three types of ligands, namely, carbene (1,3-diisopropylbenzimidazolin-2-ylidene, i Pr 2 -bimy), alkynyl (phenylacetylide, PA), and halide (Br), respectively. The delicately balanced stereochemical effects and bonding capabilities of the three ligands give rise to peculiar geometrical and electronic structures. Remarkably, des…
Atomically Precise Alkynyl- and Halide-Protected AuAg Nanoclusters Au78Ag66(C≡CPh)48Cl8 and Au74Ag60(C≡CPh)40Br12: The Ligation Effects of Halides
Reported herein are the synthesis and structures of two high-nuclearity AuAg nanoclusters, namely, [Au78Ag66(C≡CPh)48Cl8]q− and [Au74Ag60(C≡CPh)40Br12]2–. Both clusters possess a three-concentric-s...
Solubility-Driven Isolation of a Metastable Nonagold Cluster with Body-Centered Cubic Structure.
The conventional synthetic methodology of atomically precise gold nanoclusters using reduction in solutions offers only thermodynamically most stable nanoclusters. We report herein a solubility‐driven isolation strategy to access the synthesis of a metastable gold cluster. The cluster, with the composition of [Au 9 (PPh 3 ) 8 ] + ( 1 ), displays an unusual, nearly perfect body‐centered‐cubic (bcc) structure. As revealed by ESI‐MS and UV/Vis measurement, the cluster is metastable in solution and converts to the well‐known [Au 11 (PPh 3 ) 8 Cl 2 ] + ( 2 ) within just 90 min. DFT calculations revealed that while both 1 and 2 are eight‐electron superatoms, there is a driving force to convert 1 …
Combinatorial Identification of Hydrides in a Ligated Ag40 Nanocluster with Noncompact Metal Core
No formation of bulk silver hydride has been reported. Until very recently, only a few silver nanoclusters containing hydrides have been successfully prepared. However, due to the lack of effective techniques and also poor stability of hydride-containing Ag nanoclusters, the identification of hydrides' location within Ag nanoclusters is challenging and not yet achieved, although some successes have been reported on clusters of several Ag atoms. In this work, we report a detailed structural and spectroscopic characterization of the [Ag40(DMBT)24(PPh3)8H12]2+ (Ag40H12) cluster (DMBT = 2,4-dimethylbenzenethiol). The metal framework consists of three concentric shells of Ag8@Ag24@Ag8, which can…
Solvent-mediated assembly of atom-precise gold–silver nanoclusters to semiconducting one-dimensional materials
Bottom-up design of functional device components based on nanometer-sized building blocks relies on accurate control of their self-assembly behavior. Atom-precise metal nanoclusters are well-characterizable building blocks for designing tunable nanomaterials, but it has been challenging to achieve directed assembly to macroscopic functional cluster-based materials with highly anisotropic properties. Here, we discover a solvent-mediated assembly of 34-atom intermetallic gold–silver clusters protected by 20 1-ethynyladamantanes into 1D polymers with Ag–Au–Ag bonds between neighboring clusters as shown directly by the atomic structure from single-crystal X-ray diffraction analysis. Density fun…
Enhanced Surface Ligands Reactivity of Metal Clusters by Bulky Ligands for Controlling Optical and Chiral Properties.
Surface ligands play critical roles in determining the surface properties of metal clusters. However, modulating the properties and controlling the surface structure of clusters through surface‐capping agent displacement remain a challenge. In this work, a silver cluster, [Ag 14 (SPh(CF 3 ) 2 ) 12 (PPh 3 ) 4 (DMF) 4 ] ( Ag 14 ‐DMF , where HSPh(CF 3 ) 2 is 3,5‐bis(trifluoromethyl)benzenethiol, PPh 3 is triphenylphosphine and DMF is N,N‐Dimethylformamide), with weakly coordinated DMF ligands on the surface silver sites, was synthesized by using a mixed ligands strategy (bulky thiolates, phosphines and small solvents). The as‐prepared Ag 14 ‐DMF is a racemic mixture of chiral molecules. Owing …
Atomically Precise, Thiolated Copper–Hydride Nanoclusters as Single-Site Hydrogenation Catalysts for Ketones in Mild Conditions
Copper-hydrides are known catalysts for several technologically important reactions such as hydrogenation of CO, hydroamination of alkenes and alkynes, and chemoselective hydrogenation of unsaturated ketones to unsaturated alcohols. Stabilizing copper-based particles by ligand chemistry to nanometer scale is an appealing route to make active catalysts with optimized material economy; however, it has been long believed that the ligand-metal interface, particularly if sulfur-containing thiols are used as stabilizing agent, may poison the catalyst. We report here a discovery of an ambient-stable thiolate-protected copper-hydride nanocluster [Cu25H10(SPhCl2)18]3- that readily catalyzes hydrogen…
Bulky Surface Ligands Promote Surface Reactivities of [Ag141X12(S-Adm)40]3+ (X = Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles
Surface ligands play important roles in controlling the size and shape of metal nanoparticles and their surface properties. In this work, we demonstrate that the use of bulky thiolate ligands, along with halides, as the surface capping agent promotes the formation of plasmonic multiple-twinned Ag nanoparticles with high surface reactivities. The title nanocluster [Ag141X12(S-Adm)40]3+ (where X = Cl, Br, I; S-Adm = 1-adamantanethiolate) has a multiple-shell structure with an Ag71 core protected by a shell of Ag70X12(S-Adm)40. The Ag71 core can be considered as 20 frequency-two Ag10 tetrahedra fused together with a dislocation that resembles multiple-twinning in nanoparticles. The nanocluster…
Thiol-Stabilized Atomically Precise, Superatomic Silver Nanoparticles for Catalyzing Cycloisomerization of Alkynyl Amines
Abstract Both the electronic and surface structures of metal nanomaterials play critical roles in determining their chemical properties. However, the non-molecular nature of conventional nanoparticles makes it extremely challenging to understand the molecular mechanism behind many of their unique electronic and surface properties. In this work, we report the synthesis, molecular and electronic structures of an atomically precise nanoparticle, [Ag206L72]q (L = thiolate, halide; q = charge). With a four-shell Ag7@Ag32@Ag77@Ag90 Ino-decahedral structure having a nearly perfect D5h symmetry, the metal core of the nanoparticle is co-stabilized by 68 thiolate and 4 halide ligands. Both electroche…
Copper-hydride nanoclusters with enhanced stability by N-heterocyclic carbenes
AbstractCopper-hydrides have been intensively studied for a long time due to their utilization in a variety of technologically important chemical transformations. Nevertheless, poor stability of the species severely hinders its isolation, storage and operation, which is worse for nano-sized ones. We report here an unprecedented strategy to access to ultrastable copper-hydride nanoclusters (NCs), namely, using bidentate N-heterocyclic carbenes as stabilizing ligands in addition to thiolates. In this work, a simple synthetic protocol was developed to synthesize the first large copper-hydride nanoclusters (NCs) stabilized by N-heterocyclic carbenes (NHCs). The NC, with the formula of Cu31(RS)2…
Asymmetric Synthesis of Chiral Bimetallic [Ag28Cu12(SR)24]4- Nanoclusters via Ion Pairing
In this work, a facile ion-pairing strategy for asymmetric synthesis of optically active negatively charged chiral metal nanoparticles using chiral ammonium cations is demonstrated. A new thiolated chiral three-concentric-shell cluster, [Ag28Cu12(SR)24] 4- was first synthesized as a racemic mixture and characterized by single-crystal X-ray structure determination. Mass spectrometric measurements revealed relatively strong ion-pairing interactions between the anionic nanocluster and ammonium cations. Inspired by this observation, the as-prepared racemic mixture was separated into enantiomers by employing chiral quaternary ammonium salts as chiral resolution agents. Subsequently, direct asymm…
Highly Robust but Surface-Active: N-Heterocyclic Carbene-Stabilized Au25 Nanocluster as a Homogeneous Catalyst
<div> <div> <div> <p>Surface organic ligands play a critical role in stabilizing atomically precise metal nanoclusters in solutions. However, it is still challenging to prepare highly robust ligated metal nanoclusters that are surface-active for liquid-phase catalysis without any pre-treatment. Herein, we report a novel N-heterocyclic carbine-stabilized Au25 nanocluster with high thermal and air stabilities as a homogenous catalyst for cycloisomerization of alkynyl amines to indoles. The nanocluster, characterized as [Au25(iPr2-bimy)10Br7]2+ (iPr2-bimy=diisopropyl-benzilidazolium) (1), was synthesized by direct reduction of AuSMe2Cl and iPr2- bimyAuBr with NaBH4 in o…
Asymmetric Synthesis of Chiral Bimetallic [Ag28Cu12(SR)24]4– Nanoclusters via Ion Pairing
In this work, a facile ion-pairing strategy for asymmetric synthesis of optically active negatively charged chiral metal nanoparticles using chiral ammonium cations is demonstrated. A new thiolated chiral three-concentric-shell cluster, [Ag28Cu12(SR)24]4–, was first synthesized as a racemic mixture and characterized by single-crystal X-ray structure determination. Mass spectrometric measurements revealed relatively strong ion-pairing interactions between the anionic nanocluster and ammonium cations. Inspired by this observation, the as-prepared racemic mixture was separated into enantiomers by employing chiral quaternary ammonium salts as chiral resolution agents. Subsequently, direct asymm…
Highly Robust but Surface‐Active: An N‐Heterocyclic Carbene‐Stabilized Au 25 Nanocluster
Surface organic ligands play a critical role in stabilizing atomically precise metal nanoclusters in solutions. However, it is still challenging to prepare highly robust ligated metal nanoclusters that are surface-active for liquid-phase catalysis without any pre-treatment. Now, an N-heterocyclic carbene-stabilized Au25 nanocluster with high thermal and air stabilities is presented as a homogenous catalyst for cycloisomerization of alkynyl amines to indoles. The nanocluster, characterized as [Au25 (i Pr2 -bimy)10 Br7 ]2+ (i Pr2 -bimy=1,3-diisopropylbenzimidazolin-2-ylidene) (1), was synthesized by direct reduction of AuSMe2 Cl and i Pr2 -bimyAuBr with NaBH4 in one pot. X-ray crystallization…
Co-crystallization of atomically precise metal nanoparticles driven by magic atomic and electronic shells
This paper reports co-crystallization of two atomically precise, different-size ligand-stabilized nanoclusters, a spherical (AuAg)267(SR)80 and a smaller trigonal-prismatic (AuAg)45(SR)27(PPh3)6 in 1:1 ratio, characterized fully by X-ray crystallographic analysis (SR = 2,4-SPhMe2). The larger cluster has a four concentric-shell icosahedral structure of Ag@M12@M42@M92@Ag120(SR)80 (M = Au or Ag) with the inner-core M147 icosahedron observed here for metal nanoparticles. The cluster has an open electron shell of 187 delocalized electrons, fully metallic, plasmonic behavior, and a zero HOMO-LUMO energy gap. The smaller cluster has an 18-electron shell closing, a notable HOMO-LUMO energy gap and…
From Symmetry Breaking to Unraveling the Origin of the Chirality of Ligated Au13 Cu2 Nanoclusters
A general method, using mixed ligands (here diphosphines and thiolates) is devised to turn an achiral metal cluster, Au13 Cu2 , into an enantiomeric pair by breaking (lowering) the overall molecular symmetry with the ligands. Using an achiral diphosphine, a racemic [Au13 Cu2 (DPPP)3 (SPy)6 ]+ was prepared which crystallizes in centrosymmetric space groups. Using chiral diphosphines, enantioselective synthesis of an optically pure, enantiomeric pair of [Au13 Cu2 ((2r,4r)/(2s,4s)-BDPP)3 (SPy)6 ]+ was achieved in one pot. Their circular dichroism (CD) spectra give perfect mirror images in the range of 250-500 nm with maximum anisotropy factors of 1.2×10-3 . DFT calculations provided good corre…
Site Preference in Multimetallic Nanoclusters: Incorporation of Alkali Metal Ions or Copper Atoms into the Alkynyl-Protected Body-Centered Cubic Cluster [Au7Ag8(C≡CtBu)12]+
The synthesis, structure, substitution chemistry, and optical properties of the gold-centered cubic monocationic cluster [Au@Ag8@Au6(C≡CtBu)12]+ are reported. The metal framework of this cluster can be described as a fragment of a body-centered cubic (bcc) lattice with the silver and gold atoms occupying the vertices and the body center of the cube, respectively. The incorporation of alkali metal atoms gave rise to [MnAg8−nAu7(C≡CtBu)12]+ clusters (n=1 for M=Na, K, Rb, Cs and n=2 for M=K, Rb), with the alkali metal ion(s) presumably occupying the vertex site(s), whereas the incorporation of copper atoms produced [CunAg8Au7−n(C≡CtBu)12]+ clusters (n=1–6), with the Cu atom(s) presumably occup…
CCDC 2054076: Experimental Crystal Structure Determination
Related Article: Guocheng Deng, Sami Malola, Peng Yuan, Xianhu Liu, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2021|Angew.Chem.,Int.Ed.|60|12897|doi:10.1002/anie.202101141
CCDC 2044601: Experimental Crystal Structure Determination
Related Article: Xiting Yuan, Sami Malola, Guocheng Deng, Fengjiao Chen, Hannu Häkkinen, Boon K. Teo, Lansun Zheng, Nanfeng Zheng|2021|Inorg.Chem.|60|3529|doi:10.1021/acs.inorgchem.0c03462
CCDC 2050535: Experimental Crystal Structure Determination
Related Article: Hui Shen, Lingzheng Wang, Omar López-Estrada, Chengyi Hu, Qingyuan Wu, Dongxu Cao, Sami Malola, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2021|Nano Res.|14|3303|doi:10.1007/s12274-021-3389-9
CCDC 1530605: Experimental Crystal Structure Determination
Related Article: Huayan Yang, Juanzhu Yan, Yu Wang, Haifeng Su, Lars Gell, Xiaojing Zhao, Chaofa Xu, Boon K. Teo, Hannu Häkkinen , and Nanfeng Zheng|2017|J.Am.Chem.Soc.|139|31|doi:10.1021/jacs.6b10053
CCDC 2096619: Experimental Crystal Structure Determination
Related Article: Hui Shen, Zhen Xu, Lingzheng Wang, Ying-Zi Han, Xianhu Liu, Sami Malola, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2021|Angew.Chem.,Int.Ed.|60|22411|doi:10.1002/anie.202108141
CCDC 2054077: Experimental Crystal Structure Determination
Related Article: Guocheng Deng, Sami Malola, Peng Yuan, Xianhu Liu, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2021|Angew.Chem.,Int.Ed.|60|12897|doi:10.1002/anie.202101141
CCDC 2044592: Experimental Crystal Structure Determination
Related Article: Xiting Yuan, Sami Malola, Guocheng Deng, Fengjiao Chen, Hannu Häkkinen, Boon K. Teo, Lansun Zheng, Nanfeng Zheng|2021|Inorg.Chem.|60|3529|doi:10.1021/acs.inorgchem.0c03462
CCDC 1543483: Experimental Crystal Structure Determination
Related Article: Liting Ren, Peng Yuan, Haifeng Su, Sami Malola, Shuichao Lin, Zichao Tang, Boon K. Teo, Hannu Häkkinen , Lansun Zheng, and Nanfeng Zheng|2017|J.Am.Chem.Soc.|139|13288|doi:10.1021/jacs.7b07926
CCDC 1530607: Experimental Crystal Structure Determination
Related Article: Huayan Yang, Juanzhu Yan, Yu Wang, Haifeng Su, Lars Gell, Xiaojing Zhao, Chaofa Xu, Boon K. Teo, Hannu Häkkinen , and Nanfeng Zheng|2017|J.Am.Chem.Soc.|139|31|doi:10.1021/jacs.6b10053
CCDC 1530606: Experimental Crystal Structure Determination
Related Article: Huayan Yang, Juanzhu Yan, Yu Wang, Haifeng Su, Lars Gell, Xiaojing Zhao, Chaofa Xu, Boon K. Teo, Hannu Häkkinen , and Nanfeng Zheng|2017|J.Am.Chem.Soc.|139|31|doi:10.1021/jacs.6b10053
CCDC 1530604: Experimental Crystal Structure Determination
Related Article: Huayan Yang, Juanzhu Yan, Yu Wang, Haifeng Su, Lars Gell, Xiaojing Zhao, Chaofa Xu, Boon K. Teo, Hannu Häkkinen , and Nanfeng Zheng|2017|J.Am.Chem.Soc.|139|31|doi:10.1021/jacs.6b10053
CCDC 1998895: Experimental Crystal Structure Determination
Related Article: Hui Shen, Zhen Xu, Maryam Sabooni Asre Hazer, Qingyuan Wu, Jiang Peng, Ruixuan Qin, Sam Malola, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2020|Angew.Chem.,Int.Ed.|60|3752|doi:10.1002/anie.202013718
CCDC 1814032: Experimental Crystal Structure Determination
Related Article: Guocheng Deng, Sami Malola, Juanzhu Yan, Yingzi Han, Peng Yuan, Chaowei Zhao, Xiting Yuan, Shuichao Lin, Zichao Tang, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2018|Angew.Chem.,Int.Ed.|57|3421|doi:10.1002/anie.201800327
CCDC 1851619: Experimental Crystal Structure Determination
Related Article: Cunfa Sun, Nisha Mammen, Sami Kaappa, Peng Yuan, Guocheng Deng, Chaowei Zhao, Juanzhu Yan, Sami Malola, Karoliina Honkala, Hannu Häkkinen, Boon K. Teo, Nanfeng Zheng|2019|ACS Nano|13|5975|doi:10.1021/acsnano.9b02052
CCDC 2096621: Experimental Crystal Structure Determination
Related Article: Hui Shen, Zhen Xu, Lingzheng Wang, Ying-Zi Han, Xianhu Liu, Sami Malola, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2021|Angew.Chem.,Int.Ed.|60|22411|doi:10.1002/anie.202108141
CCDC 1839942: Experimental Crystal Structure Determination
Related Article: Juanzhu Yan, Sami Malola, Chengyi Hu, Jian Peng, Birger Dittrich, Boon K. Teo, Hannu Häkkinen, Lansun Zheng, Nanfeng Zheng|2018|Nat.Commun.|9|3357|doi:10.1038/s41467-018-05584-9
CCDC 1962411: Experimental Crystal Structure Determination
Related Article: Peng Yuan, Ruihua Zhang, Elli Selenius, Pengpeng Ruan, Yangrong Yao, Yang Zhou, Sami Malola, Hannu Häkkinen, Boon K. Teo, Yang Cao, Nanfeng Zheng|2020|Nat.Commun.|11|2229|doi:10.1038/s41467-020-16062-6
CCDC 1962412: Experimental Crystal Structure Determination
Related Article: Peng Yuan, Ruihua Zhang, Elli Selenius, Pengpeng Ruan, Yangrong Yao, Yang Zhou, Sami Malola, Hannu Häkkinen, Boon K. Teo, Yang Cao, Nanfeng Zheng|2020|Nat.Commun.|11|2229|doi:10.1038/s41467-020-16062-6
CCDC 1814033: Experimental Crystal Structure Determination
Related Article: Guocheng Deng, Sami Malola, Juanzhu Yan, Yingzi Han, Peng Yuan, Chaowei Zhao, Xiting Yuan, Shuichao Lin, Zichao Tang, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2018|Angew.Chem.,Int.Ed.|57|3421|doi:10.1002/anie.201800327
CCDC 1508753: Experimental Crystal Structure Determination
Related Article: Juanzhu Yan, Haifeng Su, Huayan Yang, Chengyi Hu, Sami Malola, Shuichao Lin, Boon K. Teo, Hannu Häkkinen, and Nanfeng Zheng|2016|J.Am.Chem.Soc.|138|12751|doi:10.1021/jacs.6b08100
CCDC 2054074: Experimental Crystal Structure Determination
Related Article: Guocheng Deng, Sami Malola, Peng Yuan, Xianhu Liu, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2021|Angew.Chem.,Int.Ed.|60|12897|doi:10.1002/anie.202101141
CCDC 2054073: Experimental Crystal Structure Determination
Related Article: Guocheng Deng, Sami Malola, Peng Yuan, Xianhu Liu, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2021|Angew.Chem.,Int.Ed.|60|12897|doi:10.1002/anie.202101141
CCDC 1942682: Experimental Crystal Structure Determination
Related Article: Xiting Yuan, Cunfa Sun, Xihua Li, Sami Malola, Boon K. Teo, Hannu Häkkinen, Lan-Sun Zheng, Nanfeng Zheng|2019|J.Am.Chem.Soc.|141|11905|doi:10.1021/jacs.9b03009
CCDC 2022415: Experimental Crystal Structure Determination
Related Article: Yu Wang, Haifeng Su, Liting Ren, Sami Malola, Shuichao Lin, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2016|Angew.Chem.,Int.Ed.|55|15152|doi:10.1002/anie.201609144
CCDC 2054075: Experimental Crystal Structure Determination
Related Article: Guocheng Deng, Sami Malola, Peng Yuan, Xianhu Liu, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2021|Angew.Chem.,Int.Ed.|60|12897|doi:10.1002/anie.202101141
CCDC 1811378: Experimental Crystal Structure Determination
Related Article: Juanzhu Yan, Jun Zhang, Xumao Chen, Sami Malola, Bo Zhou, Elli Selenius, Xiaomin Zhang, Peng Yuan, Guocheng Deng, Kunlong Liu, Haifeng Su, Boon K. Teo, Hannu Häkkinen, Lansun Zheng, Nanfeng Zheng|2018|National Science Review|5|694|doi:10.1093/nsr/nwy034
CCDC 2054078: Experimental Crystal Structure Determination
Related Article: Guocheng Deng, Sami Malola, Peng Yuan, Xianhu Liu, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2021|Angew.Chem.,Int.Ed.|60|12897|doi:10.1002/anie.202101141
CCDC 1967410: Experimental Crystal Structure Determination
Related Article: Hui Shen, Elli Selenius, Pengpeng Ruan, Xihua Li, Peng Yuan, Omar Lopez-Estrada, Sami Malola, Shuichao Lin, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2020|Chem.-Eur.J.|26|8465|doi:10.1002/chem.202001753
CCDC 1543485: Experimental Crystal Structure Determination
Related Article: Liting Ren, Peng Yuan, Haifeng Su, Sami Malola, Shuichao Lin, Zichao Tang, Boon K. Teo, Hannu Häkkinen , Lansun Zheng, and Nanfeng Zheng|2017|J.Am.Chem.Soc.|139|13288|doi:10.1021/jacs.7b07926
CCDC 1814031: Experimental Crystal Structure Determination
Related Article: Guocheng Deng, Sami Malola, Juanzhu Yan, Yingzi Han, Peng Yuan, Chaowei Zhao, Xiting Yuan, Shuichao Lin, Zichao Tang, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2018|Angew.Chem.,Int.Ed.|57|3421|doi:10.1002/anie.201800327
CCDC 1916156: Experimental Crystal Structure Determination
Related Article: Hui Shen, Guocheng Deng, Sami Kaappa, Tongde Tan, Ying-Zi Han, Sami Malola, Shui-Chao Lin, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2019|Angew.Chem.,Int.Ed.|58|17731|doi:10.1002/anie.201908983
CCDC 1839941: Experimental Crystal Structure Determination
Related Article: Juanzhu Yan, Sami Malola, Chengyi Hu, Jian Peng, Birger Dittrich, Boon K. Teo, Hannu Häkkinen, Lansun Zheng, Nanfeng Zheng|2018|Nat.Commun.|9|3357|doi:10.1038/s41467-018-05584-9