6533b82cfe1ef96bd128ff97
RESEARCH PRODUCT
Preparation and structure of the 17-electron (η5-C5R5)Mo(OH)2(dppe) (R=Me, Et) organometallic compounds containing two gem-terminal hydroxide ligands
Dolores MoralesBrett PleuneRinaldo PoliPhilippe Richardsubject
Hydroxide complexeschemistry.chemical_elementHalf-sandwich complexesElectronTriclinic crystal system010402 general chemistry01 natural sciencesBiochemistrylaw.inventionInorganic Chemistrychemistry.chemical_compoundTrans configurationlawOxidationMaterials ChemistryMolecule[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical ChemistryElectron paramagnetic resonanceGroup 2 organometallic chemistryMolybdenum010405 organic chemistryOrganic ChemistryHydride complexes0104 chemical sciencesCrystallographychemistryMolybdenumHydroxidedescription
International audience; Oxidation of (η5-C5R5)MoH3(dppe) (R=Me, Et) by Cp2Fe+ in wet THF leads to the formation of the corresponding (η5-C5R5)Mo(OH)2(dppe). These compounds show a low-potential reversible oxidation wave. The structure of the C5Et5 complex has been confirmed by X-ray diffraction methods: triclinic; space group ; a=11.030(1); b=12.533(1); c=16.241 (1) Å; α=68.585(7); β=75.197(5); γ=83.991(7)°; V=2020.6(3) Å3; Z=2; Dcalc=1.324 g cm−3, μ(Mo–Kα)=0.441 mm−1; R1=0.0325; wR2=0.0875 for 415 parameters and 6823 independent reflections [Rint=0.0177] with I=2σ(I). The molecule shows a four-legged piano-stool geometry with two terminal OH ligands in a relative trans configuration. The complex EPR properties indicate that an equilibrium mixture of various species is present in solution.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2000-02-01 |