6533b82dfe1ef96bd12908ff

RESEARCH PRODUCT

Tuning of the photoinduced charge transfer process in donor-acceptor "double cable" copolymers

Luzzati SMozer ADenk PScharber M. CCatellani MLupsac N. OSegura J. LMartin NNeugebauer HSariciftci N. S.Francesco Giacalone

subject

Condensed Matter PhysicConjugated systemPhotochemistryAnthraquinonePhotoinduced electron transferlaw.inventionchemistry.chemical_compoundlawMaterials ChemistryMoleculeDonor-acceptor alkylthiophene copolymerPhotoinduced charge transferElectron paramagnetic resonanceMechanical EngineeringElectronic Optical and Magnetic MaterialMetals and AlloysSettore CHIM/06 - Chimica OrganicaCondensed Matter PhysicsAcceptorElectronic Optical and Magnetic MaterialschemistryMechanics of MaterialsCovalent bondPolythiopheneLight-induced electron spin resonancePhotoinduced absorption

description

The covalent linking of acceptor molecules to electron donating conjugated polymer is an approach for the development of new photoactive materials for the fabrication of organic photoelectric conversion devices. With this strategy we have designed a polyalkylthiophene copolymer series containing in the side chain anthraquinone molecules as electron acceptor. The peculiar features of the copolymers are the good processability and the ease in tailoring the content of acceptor moieties. Their potential use as photoactive materials is investigated in terms of the photoinduced charge transfer properties, studied by FTIR photoinduced absorption and Light Induced Electron Spin Resonance spectroscopies. The results indicate the photoinduced electron transfer from the polythiophene backbone to the anthraquinone substituents and its tunability by changing the content of acceptor molecules. The photovoltaic response of these polymers is also discussed.

yearjournalcountryeditionlanguage
2003-10-01
http://hdl.handle.net/10447/1591