6533b82dfe1ef96bd1290a71

RESEARCH PRODUCT

Non-conventional methods and media for the activation and manipulation of carbon nanoforms

Maurizio PratoEster VázquezFrancesco Giacalone

subject

FullereneNanotubes Nanohorns Synthesis Microwave chemistry Ionic Liquidschemistry.chemical_elementIonic LiquidsNanotechnologylaw.inventionchemistry.chemical_compoundlawReactivity (chemistry)MicrowavesAlternative methodsGrapheneNanotubes Carboncarbon nanoforms non-conventional techniquesnon-conventional techniquesWaterGeneral ChemistrySettore CHIM/06 - Chimica OrganicaSupercritical fluidCarbonNanostructureschemistryGamma RaysIonic liquidMicrowave irradiationSolventsGraphitecarbon nanoformsCarbon

description

Very often, chemical transformations require tedious and long procedures, which, sometimes, can be avoided using alternative methods and media. New protocols, enabling us to save time and solvents, allow us also to explore new reaction profiles. This Tutorial Review focuses on the physical and chemical behavior of carbon nanoforms, CNFs (fullerenes, nanotubes, nanohorns, graphene, etc.) when non-conventional methods and techniques, such as microwave irradiation, mechano-chemistry or highly ionizing radiations are employed. In addition, the reactivity of CNFs in non-conventional media such as water, fluorinated solvents, supercritical fluids, or ionic liquids is also discussed.

10.1039/c3cs60164ahttp://hdl.handle.net/10447/85407