6533b82dfe1ef96bd129140c
RESEARCH PRODUCT
Encapsulation of diquats by resorcinarenes: a novel staggered anion–solvent mediated hydrogen bonded capsule
Heidi MansikkamäkiMaija NissinenKari Rissanensubject
HydrogenMetals and Alloyschemistry.chemical_elementCapsuleGeneral ChemistryResorcinareneCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonlaw.inventionSolventchemistry.chemical_compoundchemistrylawMaterials ChemistryCeramics and CompositesOrganic chemistryMoleculeCrystallizationOctanedescription
Crystallisation studies of ethyl resorcinarene with diquats 2b and 3a (1,4-dimethyl-1,4-diazoniabicyclo[2.2.2]octane dibromide and 1,4-diazoniabicyclo[2.2.2]octane dichloride, respectively) resulted in hydrogen bonded molecular capsules in which the cations are encapsulated in between the cavities of two resorcinarene molecules and anions are located in the middle of the lower rim ethyl chains.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-09-26 | Chem. Commun. |