6533b82dfe1ef96bd129161d

RESEARCH PRODUCT

Processing-structure-property relationships of electrospun PLA-PEO membranes reinforced with enzymatic cellulose nanofibers

Giada Lo ReAndrea MaioRobab GhafariEmmanuel Fortunato GulinoMehdi JonoobiRoberto Scaffaro

subject

Materials sciencePolymers and Plastics02 engineering and technology010402 general chemistry01 natural scienceschemistry.chemical_compoundPolylactic acidUltimate tensile strengthmedicineCellulosechemistry.chemical_classificationBionanocomposites Electrospinning Nanocellulose Polyethylene oxide Polylactic acid Raman spectroscopyOrganic Chemistrytechnology industry and agriculturePolymer021001 nanoscience & nanotechnology0104 chemical sciencesSolventSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiMembranechemistryChemical engineeringNanofiberSwellingmedicine.symptom0210 nano-technology

description

Abstract Three different solvent mixtures were used to prepare electrospun membranes based on polylactic acid (PLA), polyethylene oxide (PEO) and enzymatic cellulose nanofibers (CNF). The materials were characterized from a morphological, spectroscopic, mechanical and rheological point of view. Furthermore, swelling test were performed in order to assess the water uptake of each sample. The results put into evidence that the choice of the solvents affects the structure and the properties of the membranes. Among the protocols tested, using chloroform/acetone/ethanol mixture was found to allow a high degree of CNF dispersion and a good electrospinnability of polymer solutions. These features led to membranes with impressive improvement of mechanical properties (+350% in stiffness, +350% in tensile strength and +500% in toughness) with respect to those of PLA/PEO and dramatically increased the water uptake of these materials (up to +350% within 120 min).

yearjournalcountryeditionlanguage
2020-01-01Polymer Testing
https://doi.org/10.1016/j.polymertesting.2019.106182