6533b82dfe1ef96bd1291ca4

RESEARCH PRODUCT

Quartz-capillary gas chromatography of chlorinated phenols and catechols

I. O. O. KorhonenJuha Knuutinen

subject

chemistry.chemical_compoundChromatographychemistryChlorinated phenolsElutionOrganic ChemistryClinical BiochemistryPhenolsGas chromatographyBiochemistryQuartzCapillary gas chromatographyAnalytical Chemistry

description

The gas chromatography of all chlorinated phenols and catechols on a non-polar SE-30 quartz-capillary column has been studied. The relative retention times of the individual components are given and the elution order is discussed. All of the chlorophenols and chlorocatechols can be separated under appropriate operating conditions but simultaneous determination of all the compounds studied resulted in overlapping peaks. Theortho-effect in catechols is stronger than that in phenols. A different order of elution for the compounds studied to that of the corresponding acetate esters is found. Generally, longer retention times for the latter are observed.

https://doi.org/10.1007/bf02271039