Zur Kinetik der alkalischen Spaltung quartärer Phosphoniumsalze

6533b82efe1ef96bd12926e3

RESEARCH PRODUCT

Zur Kinetik der alkalischen Spaltung quartärer Phosphoniumsalze

subject

Chemistry Organic Chemistry Physical and Theoretical Chemistry Medicinal chemistry

description

Der zeitliche Verlauf der Spaltung von Triphenylbenzylphosphoniumsalzen durch Natriumhydroxyd entspricht in guter Naherung einem Zeitgesetz 3. Ordnung. Der Einflus von Substituenten im Benzylrest auf die Spaltungsgeschwindigkeit steht in Ubereinstimmung mit der Hammett-Gleichung. Phosphinoxyde beschleunigen die Reaktion. Salzzusatze wirken in Abhangigkeit von der Grose des Kations beschleunigend oder verzogernd.

year	journal	country	edition	language
1960-08-11	Justus Liebigs Annalen der Chemie

https://doi.org/10.1002/jlac.19606340102

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