6533b82efe1ef96bd1292711

RESEARCH PRODUCT

Bis(oxalato)chromium(III) complexes: Versatile tectons in designing heterometallic coordination compounds

Francesc LloretGabriela MarinescuGabriela MarinescuMarius AndruhMiguel Julve

subject

chemistry.chemical_classificationChromate conversion coatingbiologyChemistryStereochemistryLigandMetal ions in aqueous solutionCationic polymerizationStructural diversitychemistry.chemical_elementASPHCoordination complexInorganic ChemistryChromiumPolymer chemistryMaterials Chemistrybiology.proteinPhysical and Theoretical Chemistry

description

Abstract The mononuclear oxalato-containing chromium(III) complexes of general formula [Cr(AA)(C2O4)2]− (AA = α-diimine type ligand) are able to produce a large variety of heterometallic complexes by acting as ligands towards either fully solvated metal ions or preformed cationic complexes with available coordination sites. This review focuses on the structural diversity of the polynuclear complexes (oligonuclear and coordination polymers) which are generated by the bis(oxalato)chromate(III) species, with a special emphasis to their magnetic properties.

yearjournalcountryeditionlanguage
2011-01-01Coordination Chemistry Reviews
https://doi.org/10.1016/j.ccr.2010.08.004