6533b82efe1ef96bd12927b6
RESEARCH PRODUCT
Exchange Coupling in Cyano-Bridged Homodinuclear Cu(II) and Ni(II) Complexes: Synthesis, Structure, Magnetism, and Density Functional Theoretical Study
Michel VerdaguerSantiago AlvarezJacqueline VaissermannMiguel JulveMarvaudA. ScuillerC. DecroixAntonio Rodríguez-forteaPere AlemanyI. RosenmanEliseo Ruizsubject
Coupling constantCouplingMagnetismMetal ions in aqueous solutionExchange interactionchemistry.chemical_elementBridging ligandCopperInorganic ChemistryNickelCrystallographychemistryComputational chemistryPhysical and Theoretical Chemistrydescription
The synthesis and structural characterization of several new cyano-bridged copper(II) and nickel(II) homodinuclear complexes is presented. The measure of magnetic properties for these complexes is complemented with a computational study of the exchange coupling for several model structures representing this family of compounds. The influence of several factors on the coupling constant has been examined, coordination position occupied by the bridging ligand, distortions of the coordination environment, and relative disposition of the cyanide ion with respect to the M-M vector. Comparison of experimental and calculated coupling constants allows for the rationalization of the most relevant features of the exchange interaction between two identical metal ions through a cyano bridge.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2001-10-30 | Inorganic Chemistry |