6533b82efe1ef96bd1293acb

RESEARCH PRODUCT

Synthesis, structure and magnetic properties of the one-dimensional chain compound {K[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]·2H2O}∞

José Ramón Galán-mascarósJuan Modesto Clemente JuanKim R. Dunbar

subject

Paramagnetismchemistry.chemical_compoundCrystallographyMagnetic measurementsPentagonal bipyramidal molecular geometryChain (algebraic topology)135-TriazineChemistryCompound KGeneral ChemistryTricarboxylate

description

The one-dimensional chain compound {[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]}n−n was obtained from a reaction of 1,3,5-triazine-2,4,6-tricarboxylate with Fe(II) in water at room temperature. The high-spin Fe(II) centers adopt a pentagonal bipyramid geometry with unusual ligand binding modes. Magnetic measurements revealed weak magnetic interactions between paramagnetic centers; these were modeled with both axial and rhombic distortions.

yearjournalcountryeditionlanguage
2002-05-20Journal of the Chemical Society, Dalton Transactions
https://doi.org/10.1039/b109585b