6533b82ffe1ef96bd1294ed4
RESEARCH PRODUCT
1H and13C NMR assignments and conformational analysis of some podocarpene derivatives
Ramón J. ZaragozáM. Luisa MarinManuel ArnóMiguel A. Gonzálezsubject
Computational chemistryChemistryCarbon-13 NMR satelliteProton NMRGeneral Materials ScienceTransverse relaxation-optimized spectroscopyGeneral ChemistryFluorine-19 NMRNuclear magnetic resonance spectroscopyDEPTCarbon-13 NMRConformational isomerismdescription
This paper reports on the assignment of the 1 Ha nd 13 C NMR spectra of five podocarpene derivatives. Resonance assignments were made on the basis of one- and two-dimensional NMR techniques which included 1 H, 13 C, DEPT and HMQC and also 1D NOE difference spectroscopy. The ratio of the different conformers in the six- membered C-ring of the podocarpene system was determined by molecular mechanics calculations and analysis of proton spin-spin coupling constants. Copyright © 2000 John Wiley & Sons, Ltd.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2000-01-01 | Magnetic Resonance in Chemistry |