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RESEARCH PRODUCT
Vinyl Fluorides: Competent Olefinic Counterparts in the Intramolecular Pauson–Khand Reaction
Natalia MateuPablo BarrioMercedes Medio-simónInés LópezSantos FusteroRaquel Románsubject
010405 organic chemistryChemistryPauson–Khand reactionOrganic Chemistry010402 general chemistry01 natural sciencesBiochemistry0104 chemical scienceschemistry.chemical_compoundIntramolecular forcePolymer chemistryMoietyPhysical and Theoretical ChemistryVinyl fluoridedescription
Despite the great advances achieved in the Pauson-Khand reaction and the ever-increasing demand for fluorinated compounds, the use of vinyl fluorides as olefinic counterparts in the above-mentioned transformation had been completely overlooked. Herein, we describe, for the first time, the intramolecular Pauson-Khand reaction of enynes containing a vinyl fluoride moiety.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2019-03-30 | Organic Letters |