6533b82ffe1ef96bd1295292

RESEARCH PRODUCT

Enantiocontrol in the intermolecular cyclopropanation reaction catalyzed by dirhodium(II) complexes with ortho-metalated aryl phosphine ligands

Mario BarberisJulia Pérez-prietoPascual LahuertaMercedes Sanau

subject

CyclopropanationUNESCO::QUÍMICAMedicinal chemistry:QUÍMICA [UNESCO]CatalysisCatalysischemistry.chemical_compoundEthyl diazoacetateMaterials ChemistryOrganic chemistryPhosphine ligandsEnantiocontrol ; Intermolecular cyclopropanation ; Catalyst ; Phosphine ligandsArylIntermolecular forceMetals and AlloysEnantioselective synthesisGeneral ChemistryUNESCO::QUÍMICA::Química macromolecularSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsEnantiocontrolchemistryCeramics and Composites:QUÍMICA::Química macromolecular [UNESCO]CatalystIntermolecular cyclopropanationPhosphine

description

(P) and (M) dirhodium(II) complexes with ortho-metalated aryl phosphines are assessed as chiral catalysts in the enantioselective cyclopropanation of styrenes by ethyl diazoacetate; enantioselectivities up to 91% and up to 87%, respectively, for cis- and trans-2-arylcyclopropanecarboxylates are observed. Barberis, Mario, Mario.Barberis@uv.es ; Lahuerta Peña, Pascual, Pascual.lahuerta@uv.es ; Perez Prieto, Julia, Julia.Perez@uv.es ; Sanau Torrecilla, Mercedes, Mercedes.Sanau@uv.es

yearjournalcountryeditionlanguage
2001-01-01
http://www.scopus.com/inward/record.url?eid=2-s2.0-0035819959&partnerID=MN8TOARS