6533b82ffe1ef96bd1295a36

RESEARCH PRODUCT

ChemInform Abstract: Palladium-Polypyrrole Nanocomposites Pd@PPy for Direct C-H Functionalization of Pyrroles and Imidazoles with Bromoarenes.

Pierre BizouardJulien RogerVeronika A. ZinovyevaChristelle TestaJean-cyrille HiersoJean-cyrille Hierso

subject

chemistry.chemical_compoundNanocompositechemistryArylPolymer chemistrySurface modificationchemistry.chemical_elementNanoparticleGeneral MedicinePolypyrroleDispersion (chemistry)CatalysisPalladium

description

Palladium–polypyrrole nanocomposites (Pd@PPy) with unique combination of high palladium dispersion (nanoparticle size 2.4 nm) and high palladium content (35 wt%) are efficient catalysts for the selective arylation of substituted pyrroles and imidazoles with either activated or deactivated aryl bromides. The performances of the recoverable supported palladium catalyst matches the best performances of homogeneous systems based on Pd(OAc)2 at 0.5–0.2 mol%, and largely overwhelm the classical Pd/C catalyst.

yearjournalcountryeditionlanguage
2016-09-01ChemInform
https://doi.org/10.1002/chin.201639125