Vibrational modes of the stibine molecule

6533b830fe1ef96bd12968a8

RESEARCH PRODUCT

Vibrational modes of the stibine molecule

F. Michelot N. Sanzharov N. Sanzharov Claude Leroy L. Pluchart Elena Sergeevna Bekhtereva O.n. Ulenikov

subject

High excited levels [ PHYS.QPHY ] Physics [physics]/Quantum Physics [quant-ph]Stibine Algebraic approach Vibrational modes 01 natural sciences Molecular physics Hot band chemistry.chemical_compound [PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph]0103 physical sciences Molecular symmetry Molecule SbH3 molecule Physics::Chemical Physics Physical and Theoretical Chemistry 010306 general physics Spectroscopy Coupling Physics Quantitative Biology::Biomolecules 010304 chemical physics Group (mathematics)Operator (physics)Atomic and Molecular Physics and Optics chemistry Molecular vibration

description

International audience; In this paper, we use the algebraic approach to describe the vibrational modes of stibine molecule (of C3v molecular symmetry group) up to 21 quanta. As the stibine molecule exhibits stretch-bend resonances, we build an algebraic pyramidal coupling operator between stretching modes and bending modes adapted to this molecule. The standard deviation associated to the fit of the vibrational levels is 1.75 cm-1.

year	journal	country	edition	language
2005-08-01	Journal of Molecular Spectroscopy

https://doi.org/10.1016/j.jms.2005.03.006

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