6533b830fe1ef96bd1296f89

RESEARCH PRODUCT

Electrochemical behavior of layered annulenes

Klaus MüllenThomas A. PowersAlbert J. FryWolfgang Irmen

subject

StereochemistryOrganic ChemistryInteraction energyWeak interactionAnnuleneElectrochemistryBiochemistrychemistry.chemical_compoundChain lengthCrystallographyMonomerchemistryDrug DiscoveryChemical reductionCyclic voltammetry

description

Abstract The cyclic voltammetric behavior of a series of dimeric [14] annulenes was examined and compared with the monomer. The data suggest a signigficant degree of interaction between the annulene rings when a three-carbon chain connects them, little or no interaction with an eight-carbon chain, and weak interaction with a four-carbon chain.

https://doi.org/10.1016/s0040-4039(00)94975-x