6533b830fe1ef96bd129707e

RESEARCH PRODUCT

The influence of two different pH levels on the antioxidant properties of flavonols, flavan-3-ols, phenolic acids and aldehyde compounds analysed in synthetic wine and in a phosphate buffer

Marco GiammancoDanila Di MajoCasuccio AlessandraMaurizio La GuardiaLaura La Neve

subject

Winechemistry.chemical_classificationAntioxidantmedicine.medical_treatmentFlavonoidantioxidant activity polyphenols pH crocin red wine food compositionPhenolic acidSettore BIO/09 - FisiologiaCrocinchemistry.chemical_compoundFlavonolschemistryPolyphenolFlavanmedicineOrganic chemistryFood Science

description

Abstract The aim of this study is evaluate either the antioxidant or pro-oxidant behaviour of some typical polyphenolic compounds of red wine, to investigate the influence of two different pH levels on the antioxidant properties and to clarify their activity–structure relationship. The antioxidant activity of compounds in hydrophilic solutions at pH 3.5 and pH 7.4 were measured by a competition kinetic test, based on the crocin bleaching. The position and the number of substitution groups influence the magnitude of the antioxidant activity of the polyphenolic compounds, but their antioxidant properties are also strongly influenced by the pH conditions. Increasing the pH, a considerable increase in antioxidant capacity was observed in all compounds analysed. This study produces information about the antioxidant properties of the studied compounds at pH 3.5. It is important to clarify that the specific action measured in vitro does not necessarily reflect in vivo antioxidant properties.

https://doi.org/10.1016/j.jfca.2010.09.013